Russian Stamps?

This is the only place I can think to send this question but I'm hoping someone will have the answer. What is the difference between Russian stamps Scott 112-3 and 139-40? My catalog puts an " * Arms, Value " in the description of 112-3 but an " Surcharge " in the description of 139-40. That seems to be the only difference I can see. I have no idea what the difference between these these terms means.

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